HCID 68427706, compound → HCID 68427809, compound

HRID 1174704Notes

Reaction equation

HRID 1174704 reaction equation
[CH3:1][N:2]1[CH2:6][CH2:5][CH:4]2[N:7]([C:10]3[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=3)[CH2:8][CH2:9][CH:3]12>CO.[Pd]>[CH3:1][N:2]1[CH:3]2[CH:4]([N:7]([C:10]3[CH:15]=[CH:14][C:13]([NH2:16])=[CH:12][CH:11]=3)[CH2:8][CH2:9]2)[CH2:5][CH2:6]1

Participants

4

Reactant 1

HCID 68427706HCID 68427706, compound

Product 1

HCID 68427809HCID 68427809, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

1-Methyl-4-(4-nitrophenyl)octahydropyrrolo[3,2-b]pyrrole was hydrogenated by method B using methanol as solvent and palladium on carbon (5%) as catalyst. The product with the molecular weight of 217.32 (C13H19N3); MS (ESI): 218 (M+H+) was obtained in this way.

Workup

  1. customMS (ESI): 218 (M+H+) was obtained in this way

Sources & evidence

ORD record
ord-2eb874e0309e41a89ccb40d56673973d
Source dataset
uspto-grants-2010_11
Patent number
US07838547B2

Reaction notes

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