Styrene → HCID 68776675, compound

HRID 1176950Notes

Reaction equation

HRID 1176950 reaction equation
Br[C:2]1[C:3](=[O:18])[C:4](=[O:17])[C:5]2[CH:6]=[CH:7][C:8]3[C:13]([C:14]=2[CH:15]=1)=[CH:12][C:11](Br)=[CH:10][CH:9]=3.[CH2:19]=[CH:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[CH:19]([C:12]1[CH:11]=[CH:10][C:9]2[C:4](=[O:17])[C:3](=[O:18])[C:2]3[C:7]([C:8]=2[CH:13]=1)=[CH:6][C:5]([CH:7]=[CH:6][C:5]1[CH:14]=[CH:15][CH:2]=[CH:3][CH:4]=1)=[CH:14][CH:15]=3)=[CH:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1

Participants

3

Reactant 2

HCID 7501StyreneHCID 68775495HCID 68775495, compound

Product 1

HCID 68776675HCID 68776675, compoundYield 62%

Procedure

The Heck reaction between 3,6-dibromophenanthrenequinone (JYC-I-117-A) and styrene gave 3,6-distyrylphenanthrene-9,10-dione (JYC-I-139-A) as an orange solid in 62% yield. The scheme of the reaction is shown in FIG. 19.

Sources & evidence

ORD record
ord-47f45ff8e68d4b0e9c7da6dd12e3c050
Source dataset
uspto-grants-2010_11
Patent number
US07842830B2

Reaction notes

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