4-(3,5-Dichloro-pyridin-2-yloxy)-phenol → 4-Chlor-phenyl-methyl-carbamic acid 4-(3,5-dichloro-pyridin-2-yloxy)-phenyl ester

HRID 1179744Notes

Reaction equation

HRID 1179744 reaction equation
[Cl:1][C:2]1[C:3]([O:9][C:10]2[CH:15]=[CH:14][C:13]([OH:16])=[CH:12][CH:11]=2)=[N:4][CH:5]=[C:6]([Cl:8])[CH:7]=1.[I-].[Cl:18][C:19]1[CH:24]=[CH:23][C:22]([N:25]([CH3:34])[C:26](N2C=C[N+](C)=C2)=[O:27])=[CH:21][CH:20]=1>ClCCl>[Cl:1][C:2]1[C:3]([O:9][C:10]2[CH:15]=[CH:14][C:13]([O:16][C:26](=[O:27])[N:25]([C:22]3[CH:23]=[CH:24][C:19]([Cl:18])=[CH:20][CH:21]=3)[CH3:34])=[CH:12][CH:11]=2)=[N:4][CH:5]=[C:6]([Cl:8])[CH:7]=1

Participants

4

Reactant 2

HCID 6208804-(3,5-Dichloro-pyridin-2-yloxy)-phenolHCID 220477983-[(4-chlorophenyl)-methyl-carbamoyl]-1-methyl-3H-imidazol-1-ium iodide

Product 1

HCID 103100744-Chlor-phenyl-methyl-carbamic acid 4-(3,5-dichloro-pyridin-2-yloxy)-phenyl ester

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The title compound was prepared from 4-(3,5-dichloro-pyridin-2-yloxy)-phenol and 3-[(4-chlorophenyl)-methyl-carbamoyl]-1-methyl-3H-imidazol-1-ium iodide. The crude product was subjected to flash chromatography (Quad flash 12, dichlormethane (67%). HPLC-MS m/z=422.9 (M+1), Rt: 5.5 min.

Sources & evidence

ORD record
ord-e413d316785f4cc9882096387a0134ab
Source dataset
uspto-grants-2007_10
Patent number
US07279470B2

Reaction notes

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