HCID 11218790, compound → HCID 11313824, compound

HRID 1180791Notes

Reaction equation

HRID 1180791 reaction equation
[Si:1]([O:8][CH2:9][C:10]1([CH2:14][CH2:15]O)[CH2:13][CH2:12][CH2:11]1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[CH3:17][N:18]1[CH:22]=[CH:21][N:20]=[C:19]1[SH:23]>>[Si:1]([O:8][CH2:9][C:10]1([CH2:14][CH2:15][S:23][C:19]2[N:18]([CH3:17])[CH:22]=[CH:21][N:20]=2)[CH2:13][CH2:12][CH2:11]1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 11218790HCID 11218790, compoundHCID 178480602HCID 178480602, compound

Product 1

HCID 11313824HCID 11313824, compound

Procedure

The title compound was prepared using the same experimental procedure as in example 19a using 2-[1-({[tert-butyl(dimethyl)silyl]oxy}methyl)cyclobutyl]ethanol and 1-methyl-1H-imidazole-2-thiol. 1H NMR (300 MHz, CDCl3) δ 7.22 (s, 1H), 7.01 (s, 1H), 3.58 (s, 3H), 3.43 (s, 2H), 1.85-1.73 (m, 6H), 2.91 (t, J=6 Hz, 2H), 1.48 (s, 9H), 1.21 (t, J=4 Hz, 2H), 0.04 (s, 6H). GC-MS m/z 341 (M+H).

Sources & evidence

ORD record
ord-9c1860d01412487582ffc51098f3e984
Source dataset
uspto-grants-2007_10
Patent number
US07282512B2

Reaction notes

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