HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → Fluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | 1,3,5-Triacetoxy-hexahydro-1,3,5-triazine-2,4,6-trione | HCID 11301124 | — |
| Catalyst | Cobalt diacetate | HCID 6277 | — |
| Catalyst | Manganous Acetate | HCID 12525 | — |
| Solvent | Water | HCID 962 | — |
| Product | Fluorene | HCID 6853 | — |
| Product | Fluoreneone | HCID 22281833 | — |
Reaction Steps
A mixture of 1.00 g of fluorene, 0.055 g of 1,3,5-triacetoxy-hexahydro-1,3,5-triazine-2,4,6-trione (3% by mole relative to fluorene), 9.0 g of acetic acid, 0.008 g of cobalt(II) acetate.4 H2O and 0.007 g of manganese (II) acetate .4 H2O was stirred at 120° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield fluorenon in 93% yield at 99% conversion of fluorene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07288649B2 |
| Source dataset | uspto-grants-2007_10 |
| ORD ID | ord-a02494882177432bb4a03cc55ffcaa53 |
| Source note | uspto-grants-2007_10 |