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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1183249Generated: October 30, 2026

1-Chloro-4-nitrobenzene → 1,4-Benzenediamine, N1,N1,N4,N4-tetrakis(4-aminophenyl)-

https://huagongshe.com/reaction/1183249

Reaction equation

Participants

RoleNameHCIDCharge
Reactant1-Chloro-4-nitrobenzeneHCID 7474—
ReactantP-PhenylenediamineHCID 7814—
Product1,4-Benzenediamine, N1,N1,N4,N4-tetrakis(4-aminophenyl)-HCID 76776—

Reaction Steps

Such a diimonium compound can be synthesized, for example, as follows. That is, an Ullmann reaction product of p-phenylenediamine and 1-chloro-4-nitrobenzene, is reduced to obtain N,N,N′,N′-tetrakis(p-aminophenyl)-p-phenylenediamine which is then dissolved in N,N-dimethylformamide, and an alkyl bromide is added thereto, followed by a reaction, for example, at 130° C. for 10 hours.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08664309B2
Source datasetuspto-grants-2014_03
ORD IDord-cd93a9a0bba24425a0c99081ba9d8440
Source noteuspto-grants-2014_03