HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Chloro-4-nitrobenzene → 1,4-Benzenediamine, N1,N1,N4,N4-tetrakis(4-aminophenyl)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Chloro-4-nitrobenzene | HCID 7474 | — |
| Reactant | P-Phenylenediamine | HCID 7814 | — |
| Product | 1,4-Benzenediamine, N1,N1,N4,N4-tetrakis(4-aminophenyl)- | HCID 76776 | — |
Reaction Steps
Such a diimonium compound can be synthesized, for example, as follows. That is, an Ullmann reaction product of p-phenylenediamine and 1-chloro-4-nitrobenzene, is reduced to obtain N,N,N′,N′-tetrakis(p-aminophenyl)-p-phenylenediamine which is then dissolved in N,N-dimethylformamide, and an alkyl bromide is added thereto, followed by a reaction, for example, at 130° C. for 10 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08664309B2 |
| Source dataset | uspto-grants-2014_03 |
| ORD ID | ord-cd93a9a0bba24425a0c99081ba9d8440 |
| Source note | uspto-grants-2014_03 |