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HRID1186047

反应详情

EQUATION

反应方程式

HRID 1186047 的结构方程式

REACTANTS

反应物

3
结构：Cl.c1cc[nH+]cc1
HCID21584435

未命名化合物

结构：CC(=O)OCC(=O)C1(O)CCC2C3C[C@H](C)C4=CC(=O)C=C[C@]4(C)C3=CC[C@@]21C
HCID67284222

未命名化合物

结构：CCOC(C)([O-])[O-]
HCID86598186

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)[C@]1(C)OCC(=O)[C@]2(CCC3C4C[C@H](C)C5=CC(=O)C=C[C@]5(C)C4=CC[C@@]32C)O1
HCID67286271

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

2-((6S,10R,13S)-17-hydroxy-6,10,13-trimethyl-3-oxo-6,7,8,10,12,13,14,15,16,17-decahydro-3H-cyclopenta[a]phenanthren-17-yl)-2-oxoethyl acetate is dissolved in toluene and heated with 1.5 equivalents of ethyl orthoacetate and a trace of pyridinium hydrochloride. Ethanol is distilled off the reaction mixture to drive it to completion.

WORKUP

后处理

  1. distillationEthanol is distilled off the reaction mixture