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HRID1186643

反应详情

EQUATION

反应方程式

HRID 1186643 的结构方程式

REACTANTS

反应物

2
反应SMILES：COc1cc([N+](=O)[O-])ccc1S(=O)(=O)Cl
HCID309458

2-Methoxy-4-nitrobenzenesulfonyl chloride

C7H6ClNO5S

反应SMILES：Cc1ccccc1NS(=O)(=O)c1ccc([N+](=O)[O-])cc1
HCID779038

未命名化合物

PRODUCTS

产物

1
反应SMILES：COc1cc([N+](=O)[O-])ccc1S(=O)(=O)Nc1ccccc1C
HCID47062662

未命名化合物

收率 79%

PROCEDURE

实验过程

(RK2-063-03)I This compound was prepared according to the procedure for compound 11a except using 2-methoxy-4 nitrobenzenesulfonyl chloride. Recrystallization from DCM/Hexanes obtained the required product as brown crystals (202 mg, 79%). Mp=127-129° C.; 1H NMR (400 MHz, CDCl3) δ 8.03 (d, J=8.8 Hz, 1H), 7.85-7.88 (m, 2H), 7.14-7.11 (m, 2H), 7.06-7.04 (m, 2H), 6.76 (br s, 1H), 4.13 (s, 3H), 2.26 (s, 3H).

WORKUP

后处理

  1. custom(RK2-063-03)I This compound was prepared
  2. customRecrystallization from DCM/Hexanes