HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Phenylbenzene-1-sulfonamide → N-(3-chloro-4-oxonaphthalen-1(4H)-ylidene)biphenyl-4-sulfonamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Phenylbenzene-1-sulfonamide | HCID 5017140 | — |
| Reactant | (NE)-N-(3-chloro-4-oxonaphthalen-1-ylidene)thiophene-2-sulfonamide | HCID 22524852 | — |
| Product | N-(3-chloro-4-oxonaphthalen-1(4H)-ylidene)biphenyl-4-sulfonamide | HCID 67330872 | — |
Reaction Steps
5.2.31 N-(3-chloro-4-oxonaphthalen-1(4H)-ylidene)biphenyl-4-sulfonamide (12b) was prepared according to the procedure for 12a except using 4-biphenylsulfonamide, which afforded the title compound 154 mg (37.8%) as a yellow solid. When TiCl4.2THF and THF were used instead, the reaction afforded the title compound 586.7 mg (71.9%) as a yellow solid, m.p.: 190-192° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08673910B2 |
| Source dataset | uspto-grants-2014_03 |
| ORD ID | ord-26f843d147d943c0884511c2db0e6f5e |
| Source note | uspto-grants-2014_03 |