tert-butyl N-(3-aminophenyl)carbamate → HCID 86689995, compound
Reaction equation
O([C:9]1[CH:18]=[CH:17][C:16]2[CH2:15][CH2:14][CH2:13][CH2:12][C:11]=2[C:10]=1[N+:19]([O-:21])=[O:20])S(C(F)(F)F)(=O)=O.[NH2:22][C:23]1[CH:24]=[C:25]([NH:29][C:30](=[O:36])[O:31][C:32]([CH3:35])([CH3:34])[CH3:33])[CH:26]=[CH:27][CH:28]=1>>[N+:19]([C:10]1[C:11]2[CH2:12][CH2:13][CH2:14][CH2:15][C:16]=2[CH:17]=[CH:18][C:9]=1[NH:22][C:23]1[CH:28]=[CH:27][CH:26]=[C:25]([NH:29][C:30]([O:31][C:32]([CH3:35])([CH3:34])[CH3:33])=[O:36])[CH:24]=1)([O-:21])=[O:20]Participants
3
Procedure
1-Nitro-5,6,7,8-tetrahydronaphthalen-2-yl triflate and tert-butyl 3-aminophenylcarbamate were used in a process similar to Example 1(1) to give the titled compound.
Sources & evidence
- ORD record
- ord-2b1733dd13b049b2b3ae7b517531da45
- Source dataset
- uspto-grants-2014_03
- Patent number
- US08673915B2
Reaction notes
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