1-Nitronaphthalen-2-yl triflate → HCID 86690023, compound

HRID 1186748Notes

Reaction equation

HRID 1186748 reaction equation
O([C:9]1[CH:18]=[CH:17][C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:10]=1[N+:19]([O-:21])=[O:20])S(C(F)(F)F)(=O)=O.[CH3:22][C:23]1[O:27][C:26]([C:28]2[CH:34]=[CH:33][C:31]([NH2:32])=[CH:30][CH:29]=2)=[N:25][N:24]=1>>[N+:19]([C:10]1[C:11]2[C:16](=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH:17]=[CH:18][C:9]=1[NH:32][C:31]1[CH:30]=[CH:29][C:28]([C:26]2[O:27][C:23]([CH3:22])=[N:24][N:25]=2)=[CH:34][CH:33]=1)([O-:21])=[O:20]

Participants

3

Reactant 2

HCID 147652731-Nitronaphthalen-2-yl triflateHCID 195422444-(5-Methyl-1,3,4-oxadiazol-2-yl)aniline

Product 1

HCID 86690023HCID 86690023, compoundYield 71%

Procedure

1-Nitronaphthalen-2-yl triflate (1.67 g, 5.2 mmol) and 4-(5-methyl-[1,3,4]oxadiazol-2-yl)aniline (0.91 g, 5.2 mmol) were used in a process similar to Example 1(1) to give the titled compound (1.27 g, yield 71%).

Sources & evidence

ORD record
ord-a3d5c4e6c0054f9faa58917b7da0fe0b
Source dataset
uspto-grants-2014_03
Patent number
US08673915B2

Reaction notes

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