HCID 66598538, compound → HCID 66597873, compound

HRID 1189146Notes

Reaction equation

HRID 1189146 reaction equation
[NH:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[N:2]1.[CH3:10][Si:11]([CH3:26])([CH3:25])[C:12]#[C:13][CH2:14][CH2:15]N1C2C=CC=CC=2N=N1>>[CH3:10][Si:11]([CH3:26])([CH3:25])[C:12]#[C:13][CH2:14][CH2:15][N:2]1[N:3]=[C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][C:5]2=[N:1]1

Participants

3

Reactant 2

HCID 66598538HCID 66598538, compoundHCID 178418385HCID 178418385, compound

Product 1

HCID 66597873HCID 66597873, compoundYield 67%

Procedure

The title compounds were prepared in accordance with the general method of Example 108(A), from benzotriazole (116 mg, 0.97 mmol) to yield 157 mg (0.64 mmol, 67%) of 2-(4-trimethylsilanyl-but-3-ynyl)-2H-benzo[d][1,2,3]triazole and 1-(4-trimethylsilanyl-but-3-ynyl)-1H-benzo[d][1,2,3]triazole.

Sources & evidence

ORD record
ord-dc88174f826241dd9475cdb90f9d4a4d
Source dataset
uspto-grants-2014_03
Patent number
US08674106B2

Reaction notes

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