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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1189713Generated: November 3, 2026

4-Bromotoluene → 1,6-Dibromo-2methoxy-3-benzylnaphthalene

https://huagongshe.com/reaction/1189713

Reaction equation

Participants

RoleNameHCIDCharge
Reactant4-BromotolueneHCID 7805—
ReactantBromobenzeneHCID 7961—
Reactant2-Naphthalenecarboxylic acid, 4,7-dibromo-3-hydroxy-HCID 74502—
Product1,6-Dibromo-2methoxy-3-benzylnaphthaleneHCID 68212400—
Product1,6-Dibromo-3-benzyl-2-naphtholHCID 68212403—

Reaction Steps

Using the Example 1 compound 4,7-dibromo-3-hydroxy-2-naphthoic acid as the starting material, and 4-bromotoluene to replace bromobenzene, the procedures of Examples 3-7 were repeated to obtain compounds 1,6-dibromo-2methoxy-3-benzylnaphthalene and 1,6-dibromo-3-benzyl-2-naphthol.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08674136B2
Source datasetuspto-grants-2014_03
ORD IDord-99427cca31ee4e9ea2963227356419a9
Source noteuspto-grants-2014_03