HCID 67312590, compound → HCID 68521931, compound

HRID 1189965Notes

Reaction equation

HRID 1189965 reaction equation
[OH:1][CH:2]([C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([NH:19][C:20](=[O:28])[CH:21]([CH2:25][CH2:26][CH3:27])[CH2:22][CH2:23][CH3:24])[CH:14]=1)[CH2:3][CH2:4][NH:5][C:6](=[O:12])[O:7][C:8]([CH3:11])([CH3:10])[CH3:9].C1C=C[NH+]=CC=1.[O-][Cr](Cl)(=O)=O>>[O:1]=[C:2]([C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([NH:19][C:20](=[O:28])[CH:21]([CH2:25][CH2:26][CH3:27])[CH2:22][CH2:23][CH3:24])[CH:14]=1)[CH2:3][CH2:4][NH:5][C:6](=[O:12])[O:7][C:8]([CH3:10])([CH3:11])[CH3:9]

Participants

3

Reactant 2

HCID 67312590HCID 67312590, compoundHCID 178418287HCID 178418287, compound

Product 1

HCID 68521931HCID 68521931, compound

Procedure

Oxidation of tert-butyl 3-hydroxy-3-(3-(2-propylpentanamido)phenyl)propylcarbamate by PCC following the method used in Example 16 gives tert-butyl 3-oxo-3-(3-(2-propylpentanamido)phenyl)propylcarbamate.

Sources & evidence

ORD record
ord-38b86193a2dc410dba2ac931db83a576
Source dataset
uspto-grants-2014_03
Patent number
US08674137B2

Reaction notes

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