HCID 67296362, compound → HCID 68520957, compound

HRID 1189966Notes

Reaction equation

HRID 1189966 reaction equation
[OH:1][CH:2]([C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([NH:19][S:20]([CH:23]([CH2:27][CH2:28][CH3:29])[CH2:24][CH2:25][CH3:26])(=[O:22])=[O:21])[CH:14]=1)[CH2:3][CH2:4][NH:5][C:6](=[O:12])[O:7][C:8]([CH3:11])([CH3:10])[CH3:9].C1C=C[NH+]=CC=1.[O-][Cr](Cl)(=O)=O>>[O:1]=[C:2]([C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([NH:19][S:20]([CH:23]([CH2:27][CH2:28][CH3:29])[CH2:24][CH2:25][CH3:26])(=[O:22])=[O:21])[CH:14]=1)[CH2:3][CH2:4][NH:5][C:6](=[O:12])[O:7][C:8]([CH3:11])([CH3:10])[CH3:9]

Participants

3

Reactant 2

HCID 67296362HCID 67296362, compoundHCID 178418287HCID 178418287, compound

Product 1

HCID 68520957HCID 68520957, compound

Procedure

Oxidation of tert-butyl 3-hydroxy-3-(3-(1-propylbutylsulfonamido)phenyl)propylcarbamate by PCC following the method used in Example 16 gives tert-butyl 3-oxo-3-(3-(1-propylbutylsulfonamido)phenyl)propylcarbamate.

Sources & evidence

ORD record
ord-3091b855509a4988893291168e149291
Source dataset
uspto-grants-2014_03
Patent number
US08674137B2

Reaction notes

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