2,4-Dichlorobenzenethiol → HCID 46932242, compound

HRID 1192059Notes

Reaction equation

HRID 1192059 reaction equation
Cl[C:2]1[S:6][C:5]([C:7]([C:9]2[CH:14]=[CH:13][CH:12]=[C:11]([N+:15]([O-:17])=[O:16])[CH:10]=2)=[O:8])=[CH:4][C:3]=1[N+:18]([O-:20])=[O:19].[Cl:21][C:22]1[CH:27]=[C:26]([Cl:28])[CH:25]=[CH:24][C:23]=1[SH:29]>>[Cl:21][C:22]1[CH:27]=[C:26]([Cl:28])[CH:25]=[CH:24][C:23]=1[S:29][C:2]1[S:6][C:5]([C:7]([C:9]2[CH:14]=[CH:13][CH:12]=[C:11]([N+:15]([O-:17])=[O:16])[CH:10]=2)=[O:8])=[CH:4][C:3]=1[N+:18]([O-:20])=[O:19]

Participants

3

Reactant 2

HCID 707302,4-DichlorobenzenethiolHCID 86664722HCID 86664722, compound

Product 1

HCID 46932242HCID 46932242, compound

Procedure

Prepared according to the procedure described for example 18 from (5-chloro-4-nitro-2-thienyl)-(3-nitrophenyl)methanone (100 mg, 0.28 mmol) and 2,4-dichlorobenzenethiol (50 mg, 0.28 mmol). The title compound was obtained as a solid (35 mg, 28% yield). 1H NMR (400 MHz, d6-DMSO) δ: 8.52 (2H, m), 8.26 (1H, m), 8.24 (1H, m), 8.11 (1H, m) 8.04 (1H, m), 7.87 (1H, m), 7.74 (1H, m).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-b3e5707efbe4452bb509d39fb8ab1589
Source dataset
uspto-grants-2014_03
Patent number
US08680139B2

Reaction notes

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