N~3~,N~3~-Dimethyl-1-phenylpropane-1,3-diamine → HCID 67494896, compound

HRID 1192262Notes

Reaction equation

HRID 1192262 reaction equation
[S:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[C:2]1[S:10][C:11]1[S:15][C:14]([C:16]([OH:18])=O)=[CH:13][C:12]=1[N+:19]([O-:21])=[O:20].[CH3:22][N:23]([CH3:34])[CH2:24][CH2:25][CH:26]([C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[NH2:27]>>[S:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[C:2]1[S:10][C:11]1[S:15][C:14]([C:16]([NH:27][CH:26]([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)[CH2:25][CH2:24][N:23]([CH3:34])[CH3:22])=[O:18])=[CH:13][C:12]=1[N+:19]([O-:21])=[O:20]

Participants

3

Reactant 2

HCID 25248080N~3~,N~3~-Dimethyl-1-phenylpropane-1,3-diamineHCID 60207480HCID 60207480, compound

Product 1

HCID 67494896HCID 67494896, compound

Procedure

Prepared according to the procedure described for example 44 from 5-(1,3-benzothiazol-2-ylsulfanyl)-4-nitro-thiophene-2-carboxylic acid as in step A of example 256 (34 mg, 0.1 mmol) and N′,N′-dimethyl-1-phenyl-propane-1,3-diamine (21.3 mg, 0.12 mmol). The title compound was obtained as a solid (6.5 mg, 13% yield). MS m/z: 499.08, 501.07 [M+H]+.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-a7e9a76645d346f8ab94beccd2cba749
Source dataset
uspto-grants-2014_03
Patent number
US08680139B2

Reaction notes

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