Lithium methanolate → HCID 86665003, compound

HRID 1192849Notes

Reaction equation

HRID 1192849 reaction equation
[Cl-:1].[Cl-].[Cl-].[C:4]([C:8]1[N-:9][C:10]([C:17]([CH3:20])([CH3:19])[CH3:18])=[C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])[N:12]=1)([CH3:7])([CH3:6])[CH3:5].[Ti+4:21].[CH3:22][O-:23].[Li+]>>[CH3:22][O-:23].[Cl-:1].[Cl-:1].[C:4]([C:8]1[N-:12][C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])=[C:10]([C:17]([CH3:20])([CH3:19])[CH3:18])[N:9]=1)([CH3:7])([CH3:6])[CH3:5].[Ti+4:21]

Participants

3

Reactant 2

HCID 4177230Lithium methanolateHCID 86665002HCID 86665002, compound

Product 1

HCID 86665003HCID 86665003, compound

Procedure

Solution of 0.200 g (0.51 mmol) of titanium 2,4,5-tri-tert-butyl-imidazolate trichloride in 2 ml of d8-toluene was added to 0.08 g (2.11 mmol) of lithium methoxide at RT in a small vail inside nitrogen purged glove box. The slurry was agitated at RT for 16 hours and filtered. Solution analysis by 1H and 13C NMR indicated ˜78% conversion into titanium 2,4,5-tri-tert-butyl-imidazolatedichloride methoxide:

Workup

  1. filtrationfiltered

Sources & evidence

ORD record
ord-1a2a458212784187af08616c679cd9e6
Source dataset
uspto-grants-2014_03
Patent number
US08680289B2

Reaction notes

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