Toluene → HCID 67036138, compound

Participants

Reaction Steps

As in reaction conditions of Example XIX Step 2, to 1.81 mL of toluene, the 0.01 g carbonylchlorohydridebis(tricyclohexylphosphine)ruthenium(H) was added, and the reaction was carried out between the 1-{[3-methyl-3-(trimethylsiloxy)-1-pentynyl]dimethylsilyl}-2-(dimethylvinylsilyl)ethane obtained in Step 1 and 0.57 g 4-chlorostyrene. Product was separated under the purification conditions of Example XII. The product, 1-{[3-methyl-3-(trimethylsiloxy)-1-pentynyl]dimethylsilyl}-2-{[(E)-4-chlorostyryl]dimethylsilyl)ethane, was obtained with a total yield of 82% pure product in the form of an oily, yellow liquid.

Provenance & Evidence