3-(3,5-Dichlorophenyl)propylazide → 3-(3,5-Dichlorophenyl)propan-1-amine

HRID 1193609Notes

Reaction equation

HRID 1193609 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH2:9][CH2:10][CH2:11][N:12]=[N+]=[N-])[CH:5]=[C:6]([Cl:8])[CH:7]=1>[Ni]>[Cl:1][C:2]1[CH:3]=[C:4]([CH2:9][CH2:10][CH2:11][NH2:12])[CH:5]=[C:6]([Cl:8])[CH:7]=1

Participants

3

Reactant 1

HCID 145813163-(3,5-Dichlorophenyl)propylazide

Product 1

HCID 145813173-(3,5-Dichlorophenyl)propan-1-amineYield 100.7%

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

3-(3,5-Dichlorophenyl)propylazide (0.0506 mol) was reacted with Raney nickel substantially as described in Example 7F above to obtain 10.4 g (100%) of an oily product.

Sources & evidence

ORD record
ord-a6cbd24a32824645bf0f0f39d4110928
Source dataset
uspto-grants-1989_03
Patent number
US04810811

Reaction notes

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