1-[4-Methyl-4-(4-methylphenyl)pent-1-en-1-yl]-3-phenoxybenzene → Benzene, 1-[4-methyl-4-(4-methylphenyl)pentyl]-3-phenoxy-

HRID 1194399Notes

Reaction equation

HRID 1194399 reaction equation
[O:1]([C:8]1[CH:9]=[C:10]([CH2:14][CH:15]=[CH:16][C:17]([C:20]2[CH:25]=[CH:24][C:23]([CH3:26])=[CH:22][CH:21]=2)([CH3:19])[CH3:18])[CH:11]=[CH:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.O(C1C=C(C=CCC(C2C=CC(C)=CC=2)(C)C)C=CC=1)C1C=CC=CC=1.[H][H]>C([O-])(=O)C>[O:1]([C:8]1[CH:9]=[C:10]([CH2:14][CH2:15][CH2:16][C:17]([C:20]2[CH:21]=[CH:22][C:23]([CH3:26])=[CH:24][CH:25]=2)([CH3:18])[CH3:19])[CH:11]=[CH:12][CH:13]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

5

Reactant 3

HCID 537952381-[4-Methyl-4-(4-methylphenyl)pent-1-en-1-yl]-3-phenoxybenzeneHCID 543268531-[4-Methyl-4-(4-methylphenyl)pent-2-en-1-yl]-3-phenoxybenzeneHCID 178418361HCID 178418361, compound

Product 1

HCID 11013368Benzene, 1-[4-methyl-4-(4-methylphenyl)pentyl]-3-phenoxy-

Reagents, catalysts & solvents 1

HCID 175AcetateSolvent

Procedure

To 30 ml of ethyle acetate, 1.9 g of a mixture of 50% 1-(3-phenoxyphenyl)-4-(4-methylphenyl)-4-methyl-2-pentene and 50% 1-(3-phenoxyphenyl)-4-(4-methylphenyl)-4-methyl-1-pentene was added and dissolved, and thereto 0.4 g of 5% pd-C was added, and the mixture was stirred under a pressure of 20 kg/cm2G with hydrogen gas at room temperature. After three hours, pd-C was removed by filtration, and ethyl acetate was evaporated under reduced pressure.

Workup

  1. dissolutiondissolved
  2. addition0.4 g of 5% pd-C was added
  3. custompd-C was removed by filtration, and ethyl acetate
  4. customwas evaporated under reduced pressure

Sources & evidence

ORD record
ord-cac07f5666db4f5e976137e027b8931d
Source dataset
uspto-grants-1989_03
Patent number
US04814340

Reaction notes

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