HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → 1,3-Diamino-2-(4-methoxyphenyl)imidazolium chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | O-(Diphenylphosphinyl)hydroxylamine | HCID 10955453 | — |
| Reactant | 1-Amino-2-(p-methoxyphenyl)imidazole | HCID 22167398 | — |
| Product | 1,3-Diamino-2-(4-methoxyphenyl)imidazolium chloride | HCID 70360942 | — |
Reaction Steps
0.1 g of 1-amino-2-(4-methoxyphenyl)imidazole is dissolved in 10 ml of dichloromethane. The solution is treated portionwise during 8 days with 0.29 g of O-diphenylphosphinylhydroxylamine, evaporated and the residue is suspended in 10 ml of water. The difficultly soluble diphenylphosphinic acid is removed by filtration and the filtrate is placed on a column loaded with Amberlite IRA 400 (chloride), whereupon the column is eluted with water. There is obtained 1,3-diamino-2-(4-methoxyphenyl)imidazolium chloride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04814332 |
| Source dataset | uspto-grants-1989_03 |
| ORD ID | ord-75439abee5ba4a92a810ceec45b5a418 |
| Source note | uspto-grants-1989_03 |