Aluminum(III) Chloride → HCID 13909843, compound

HRID 1194628Notes

Reaction equation

HRID 1194628 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]=[C:9]2[N:17]3[N:12]([CH2:13][CH2:14][CH2:15][CH2:16]3)[C:11](=[O:18])[S:10]2)=[CH:4][C:3]=1[O:19]C(C)C.[Cl-].[Al+3].[Cl-].[Cl-]>C(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]=[C:9]2[N:17]3[N:12]([CH2:13][CH2:14][CH2:15][CH2:16]3)[C:11](=[O:18])[S:10]2)=[CH:4][C:3]=1[OH:19]

Participants

4

Reactant 2

HCID 6451240Aluminum(III) ChlorideHCID 13909831HCID 13909831, compound

Product 1

HCID 13909843HCID 13909843, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Into a reaction flask equipped with a Dimroth condenser, 1.7 g (5 mmol) of 9-(4-chloro-3-isopropoxyphenylimino)-8-thia-1,6-diazabicyclo[4.3.0]nonane-7-one, 1.3 g (10 mmol) of aluminum chloride and 50 ml of chloroform, were charged, and refluxed under heating for 2 hours to complete the reaction.

Workup

  1. additionwere charged
  2. temperaturerefluxed
  3. temperatureunder heating for 2 hours
  4. customthe reaction

Sources & evidence

ORD record
ord-3fd9d63e163b46bfaf0774c260b6b691
Source dataset
uspto-grants-1989_03
Patent number
US04816063

Reaction notes

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