Benzoyl Peroxide → HCID 23036223, compound

HRID 1194742Notes

Reaction equation

HRID 1194742 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH3:14])[CH:5]=[C:6]([Cl:13])[C:7]=1[C:8]([Cl:12])=[C:9]([Cl:11])[Cl:10].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:33]N1C(=O)CCC1=O>C1C=CC=CC=1>[Cl:1][C:2]1[CH:3]=[C:4]([CH:5]=[C:6]([Cl:13])[C:7]=1[C:8]([Cl:12])=[C:9]([Cl:10])[Cl:11])[CH2:14][Br:33]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 23036212HCID 23036212, compound

Product 1

HCID 23036223HCID 23036223, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

From the reaction of 3,5-dichloro-4-(trichlorovinyl)toluene (2.15 g), dibenzoyl peroxide (0.33 g), and N-bromosuccinimide (2.05 g) in 85 ml of benzene at reflux as in Example 30, 3,5-dichloro-4-(trichlorovinyl)benzyl bromide is obtained. This material (2.7 g) and sodium azide (0.8 g) in ethanol (25 ml) is heated for 2 hours. The crude product is chromatographed on silica gel to give pure 3,5-dichloro-4-(trichlorovinyl)benzyl azide.

Workup

  1. temperatureat reflux as in Example 30

Sources & evidence

ORD record
ord-d9f34f77bd424468807058c0fcd5ab4b
Source dataset
uspto-grants-1989_03
Patent number
US04816469

Reaction notes

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