HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1195420Generated: November 1, 2026
Methyl Methanesulfonate → HCID 19819114, compound
https://huagongshe.com/reaction/1195420
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methyl Methanesulfonate | HCID 4156 | — |
| Reactant | 2-Chloroethyl isocyanate | HCID 16035 | — |
| Catalyst | N,N,N-Tributylbutan-1-aminium methanesulfonate | HCID 3017603 | — |
| Product | HCID 19819114 | HCID 19819114 | — |
Reaction Steps
20.0 g (0.06 mol) of tetrabutylammonium methanesulfonate are added to a solution of 36.0 g (0.34 mol) of 2-chloroisocyanatoethane and 93.3 g (0.85 mol) of methyl methanesulfonate and the mixture is heated at 120° C for 6 hours. It is distilled in a thin layer evaporator at 180° C. under a pressure of 0.04 mbar and the crude product is purified by distillation. 18.0 g (0.17 mol) of 2chloroisocyanatoethane and 71.0 g (0.65 mol) of methyl methanesulfonate are recovered in this way.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05110975 |
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| Source dataset | uspto-grants-1992_05 |
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| ORD ID | ord-d433e79b626e43a59a3c9c476aee80f4 |
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| Source note | uspto-grants-1992_05 |
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