HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ethylamine → dihydro-2,2,5,5-tetramethyl-4-ethylaminomethylene-3(2H)furanone
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ethylamine | HCID 6341 | — |
| Edukt | 4-hydroxymethylene-dihydro-2,2,5,5-tetramethyl-3(2H)-furanone | HCID 67574879 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | dihydro-2,2,5,5-tetramethyl-4-ethylaminomethylene-3(2H)furanone | HCID 53707148 | 65% |
Reaktionsschritte
Ethylamine gas was bubbled through a solution of 4-hydroxymethylene-dihydro-2,2,5,5-tetramethyl-3(2H)furanone (4.0 g, 24 mmol) in 50 mL of chloroform at room temperature for 15 min. The solvents were evaporated and the residue was recrystallized from hexanes to give 3.0 g (65%) of dihydro-2,2,5,5-tetramethyl-4-ethylaminomethylene-3(2H)furanone as a light brown solid.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05112595 |
| Quelldatensatz | uspto-grants-1992_05 |
| ORD ID | ord-93d83998f7384833bbbc01f2c60aee3a |
| Quellennotiz | uspto-grants-1992_05 |