3',4',5'-Trimethoxyacetophenone → HCID 53775759, compound

HRID 1195936Notes

Reaction equation

HRID 1195936 reaction equation
[OH:1][C:2]1[CH:3]=[C:4]([CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[OH:10])[CH:5]=O.[CH3:14][O:15][C:16]1[CH:17]=[C:18]([C:26](=[O:28])[CH3:27])[CH:19]=[C:20]([O:24][CH3:25])[C:21]=1[O:22][CH3:23]>>[OH:1][C:2]1[CH:3]=[C:4]([CH:5]=[CH:27][C:26]([C:18]2[CH:19]=[C:20]([O:24][CH3:25])[C:21]([O:22][CH3:23])=[C:16]([O:15][CH3:14])[CH:17]=2)=[O:28])[CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[OH:10]

Participants

3

Reactant 2

HCID 143453',4',5'-TrimethoxyacetophenoneHCID 57489573,4-Dihydroxy-5-nitrobenzaldehyde

Product 1

HCID 53775759HCID 53775759, compound

Procedure

The procedure described in Example 8 was repeated using 0.55 g of 3,4-dihydroxy-5-nitrobenzaldehyde and 0.63 g of 3',4',5'-trimethoxyacetophenone. Yield 0.50 g (44%), m.p. 213°-216° C.

Sources & evidence

ORD record
ord-8babd86905f047ef980b91baa7937457
Source dataset
uspto-grants-1992_05
Patent number
US05112861

Reaction notes

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