2'-Hydroxyacetophenone → HCID 54439145, compound

HRID 1195937Notes

Reaction equation

[OH:1][C:2]1[CH:3]=[C:4]([CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[OH:10])[CH:5]=O.[OH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=1[C:21](=[O:23])[CH3:22]>>[OH:1][C:2]1[CH:3]=[C:4]([CH:5]=[CH:22][C:21]([C:16]2[CH:17]=[CH:18][CH:19]=[CH:20][C:15]=2[OH:14])=[O:23])[CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[OH:10]

Participants

Reactant 2

HCID 83752'-Hydroxyacetophenone

HCID 57489573,4-Dihydroxy-5-nitrobenzaldehyde

Product 1

HCID 54439145HCID 54439145, compound

Procedure

The procedure described in Example 8 was repeated using 1.0 g of 3,4-dihydroxy-5-nitrobenzaldehyde and 0.74 g of 2'-hydroxyacetophenone. Yield 0.2 g (12%), m.p. 231°-234° C.

Sources & evidence

ORD record: ord-d80e9dbfe5d5471bbe1bc9b0a6f96828
Source dataset: uspto-grants-1992_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05112861

Reaction notes

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