HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 15030135, compound → HCID 15030120, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 15030135 | HCID 15030135 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 15030120 | HCID 15030120 | 125.7% |
Reaction Steps
Similarly 1.0 g of (-)-3-(4-morpholinylmethyl)5-methyl-6-phenylthio-2,3-dihydropyrrolo[1,2,3-de]-1,4-benzoxazine in 100 ml of ethanol was reduced with one teaspoon of Raney nickel to give 0.9 g of (-)-3-(4-morpholinylmethyl)-5-methyl-2,3-dihydropyrrolo[1,2,3-de]-1,4-benzoxazine, [α]D25 =-63°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05112820 |
| Source dataset | uspto-grants-1992_05 |
| ORD ID | ord-588cd3f360bb40129a2addfb86fe10f7 |
| Source note | uspto-grants-1992_05 |