Dichloroacetyl chloride → HCID 53837823, compound

HRID 1196404Notes

Reaction equation

HRID 1196404 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:14]=[CH:15][CH:16]=1)[CH2:5][NH:6][CH2:7][CH:8]=[CH:9][CH2:10][CH2:11]CC.[Cl:17][CH:18]([Cl:22])[C:19](Cl)=[O:20]>C1(C)C=CC=CC=1>[Cl:1][C:2]1[CH:3]=[C:4]([CH:14]=[CH:15][CH:16]=1)[CH2:5][N:6]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:19](=[O:20])[CH:18]([Cl:22])[Cl:17]

Participants

4

Reactant 2

HCID 6593Dichloroacetyl chlorideHCID 54252010HCID 54252010, compound

Product 1

HCID 53837823HCID 53837823, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

2 g of N-(3-chlorobenzyl)-N-(2-heptenyl)amine was dissolved in 40 ml of toluene, to which 1.7 g of 2,2-dichloroacetyl chloride was dropped under stirring gradually at a room temperature. After stirring for 20 min, deposited insoluble matters were filtered and then 50 ml of toluene was added. The toluene solution was washed with an aqueous saturated solution of sodium hydrogen carbonate and with a saturated solution of sodium chloride respectively each by twice. After dying with anhydrous sodium sulfate, it was concentrated in an evaporated to obtain an aimed oily product quantitatively.

Workup

  1. additionwas dropped
  2. stirringAfter stirring for 20 min
  3. filtrationwere filtered
  4. addition50 ml of toluene was added
  5. washThe toluene solution was washed with an aqueous saturated solution of sodium hydrogen carbonate and with a saturated solution of sodium chloride respectively each by twice
  6. concentrationwas concentrated in
  7. customan evaporated
  8. customto obtain an aimed oily product quantitatively

Sources & evidence

ORD record
ord-8bfb86e2da43474d82856064b04c61ec
Source dataset
uspto-grants-1992_05
Patent number
US05114466

Reaction notes

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