Toluene → HCID 87097284, compound

HRID 1196453Notes

Reaction equation

HRID 1196453 reaction equation
ClC(Cl)(Cl)C(Cl)(Cl)Cl.[Ti:9]([Cl:13])([Cl:12])([Cl:11])[Cl:10].[C:14]1([CH3:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[Ti:9]([Cl:13])([Cl:12])([Cl:11])[Cl:10].[C:14]1([CH3:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

4

Reactant 3

HCID 1140Toluene2×HCID 6214HexachloroethaneHCID 24193Titanium Tetrachloride

Product 1

HCID 87097284HCID 87097284, compound

Procedure

22.4 ml of toluene and 22.8 ml of a toluene solution of hexachloroethane (0.43 ml/l) were added to Solid B obtained as described above and stirred at room temperature for 15 minutes. Titanium tetrachloride was then added so as to give a titanium tetrachloride/toluene volume ratio of 3/2 and heated to 95° C., followed by stirring for 2 hours. The resulting solid material was washed 6 times respectively with 120 ml of n-hexane at 85° C. and further subjected to drying under reduced pressure for 1 hour to obtain 8.1 g of a catalytic component containing 2.8% of titanium.

Workup

  1. customobtained

Sources & evidence

ORD record
ord-c13d956b4a1e4dbda72ee423b08fa642
Source dataset
uspto-grants-1992_05
Patent number
US05114896

Reaction notes

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