Vinyl Acetate → 2-Chloro-1,1-diethoxyethane

HRID 1196756Notes

Reaction equation

HRID 1196756 reaction equation
[C:1]([O:4][CH:5]=[CH2:6])(=[O:3])[CH3:2].[Cl:7]Cl.C[C:10]([CH3:12])=O.C(O)C>>[CH2:5]([O:4][CH:1]([O:3][CH2:10][CH3:12])[CH2:2][Cl:7])[CH3:6]

Participants

4

Reactant 3

HCID 7904Vinyl AcetateHCID 24526ChlorineHCID 21889777Acetone ethanol

Product 1

HCID 121282-Chloro-1,1-diethoxyethane

Procedure

To a mixture of 5 g of vinyl acetate and 27 ml of ethanol acetone cooled on dry ice 5 g of dry chlorine gas are added, then it is left standing for a night at room temperature. The reaction is poured onto 50 g of ice-water. The product is extracted with 30 ml of chloroform, the extract is washed with a sodium hydrogen carbonate solution and water, then dried on magnesium sulfate and distilled.

Workup

  1. additionare added
  2. waitit is left
  3. waitstanding for a night at room temperature
  4. extractionThe product is extracted with 30 ml of chloroform
  5. washthe extract is washed with a sodium hydrogen carbonate solution and water
  6. customdried on magnesium sulfate
  7. distillationdistilled

Sources & evidence

ORD record
ord-8504bce0c1c34756a889055a56a5bab2
Source dataset
uspto-grants-1992_05
Patent number
US05116402

Reaction notes

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