HRID1196794

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10868

Dicyclohexylcarbodiimide

C13H22N2

HCID21885

2-Dimethylaminopyridine

C7H10N2

HCID11010379

未命名化合物

2 次

结构：CCCCCCCCC(=O)Oc1ccc(-c2ccc(C(=O)O)cc2)cc1

HCID13668451

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCC(=O)Oc1ccc(-c2ccc(C(=O)Oc3ccc(C(=O)OC(C)CCCCCC)cc3)cc2)cc1

HCID15919277

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

In 330 ml of dehydrated tetrahydrofuran were dissolved 5.00 g of 4'-nonanoyloxybiphenyl-4-carboxylic acid and 6.76 g of 1-methylheptyl 4-hydroxybenzoate synthesized in (2) above. To the solution were added 6.18 g of DCC and 0.24 g of dimethylaminopyridine, followed by stirring for one day at room temperature.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-bf99518655ed4455b7ae0f2d46f54000
来源数据集: uspto-grants-1992_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05116531
来源说明: uspto-grants-1992_05

反应 SMILES

[C:1]([O:11][C:12]1[CH:17]=[CH:16][C:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([OH:26])=[O:25])=[CH:20][CH:19]=2)=[CH:14][CH:13]=1)(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].O[C:28]1[CH:44]=[CH:43][C:31]([C:32]([O:34][CH:35]([CH3:42])[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41])=[O:33])=[CH:30][CH:29]=1.C1CCC(N=C=NC2CCCCC2)CC1.CN(C1C=CC=CN=1)C>O1CCCC1>[C:1]([O:11][C:12]1[CH:13]=[CH:14][C:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([O:26][C:28]3[CH:44]=[CH:43][C:31]([C:32]([O:34][CH:35]([CH3:42])[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41])=[O:33])=[CH:30][CH:29]=3)=[O:25])=[CH:20][CH:19]=2)=[CH:16][CH:17]=1)(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]