Dichloromethane → HCID 19896627, compound

Participants

Reaction Conditions

Reaction Steps

A cold (5° C.) solution of p-(methylthio)benzyl p-nitrobenzyl carbonate (1.0 g, 3 mmol) in CH2Cl2 (50 mL) was treated dropwise (2 min) with S02Cl2 (0.425 g, 3.15 mmol). After stirring the resulting solution for 30 min at 5° C., the solvent was evaporated to leave the title compound as an oil which solidified (1.10 g yield, 99.7%). The solid was used without purification in the next step.

Provenance & Evidence