Platinum(2+) → HCID 22808639, compound

HRID 1197201Notes

Reaction equation

[NH2:1][C@@H:2]1[CH2:7][CH2:6][CH2:5][CH2:4][C@@H:3]1[NH2:8].[Pt+2:9]>>[Pt+2:9].[NH2:1][C@@H:2]1[CH2:7][CH2:6][CH2:5][CH2:4][C@@H:3]1[NH2:8]

Participants

Reactant 2

HCID 105166Platinum(2+)2×

HCID 3429171,2-Diaminocyclohexane, cis-

Product 1

HCID 22808639HCID 22808639, compound

Procedure

Complex #27, cis-bis-neodecanoato (cis-1,2-diaminocyclohexane) platinum (II) was synthesized according to synthetic route #1 using an isomeric mixture of neodecanoic acids and cis-1,2-diaminocyclohexane (DACH). The general structure of cis-bis-Neodecanoato (cis-1,2-DACH) platinum (II) is as follows: ##STR33## where R,R' and R" are each methyl, ethyl, propyl or isopropyl and together have eight carbon atoms. Elemental analysis of cis-bis-Neodecanoato (cis-1,2-DACH) platinum (II) showed respective percentages for C; H; and N of 46.86%; 8.13%; and 4.27%; as compared to the calculated percentages of 46.23%; 7.70%; and 4.49%.

Sources & evidence

ORD record: ord-40bc2a9ee462418288f9f9d4837bacde
Source dataset: uspto-grants-1992_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05117022

Reaction notes

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