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Water → N'-t-butyl-N-benzoyl-N'-(2-furoyl)hydrazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 2-Furancarbonyl chloride | HCID 68242 | — |
| 反応物 | N'-tert-butylbenzohydrazide | HCID 299436 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | N'-t-butyl-N-benzoyl-N'-(2-furoyl)hydrazine | HCID 15452001 | — |
反応手順
N'-t-butyl-N-benzoylhydrazine (1 g) was dissolved in 20 ml toluene. Water (5 ml) and 50% aqueous sodium hydroxide (1.25 g) was added followed by 2-furoylchloride (0.68 g). After stirring for 7 hours at room temperature, 0.3 g 2-furoylchloride was added and the mixture stirred for a further 6 hours. The solid product, N'-t-butyl-N-benzoyl-N'-(2-furoyl)hydrazine, was removed by filtration and washed with water. m.p. 155°-175° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05117057 |
| 出典データセット | uspto-grants-1992_05 |
| ORD ID | ord-39d3585525404da5b6dc441f4856ddb6 |
| 出典メモ | uspto-grants-1992_05 |