HuagongsheHuagongshe Chemistry Print Report · For research reference only
4,4-Dimethylpentanoic acid → 4-t-Butyl-1-(3,3-dimethylbut-1-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4,4-Dimethylpentanoic acid | HCID 14237 | — |
| Reactant | 4-t-Butyl-1-(3,3-dimethylbutyl)-2,6,7-trioxabicyclo[2.2.2]octane | HCID 19373262 | — |
| Reactant | 1-(3,3-Dimethylbutyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane-3-carbonitrile | HCID 19373351 | — |
| Product | 4-t-Butyl-1-(3,3-dimethylbut-1-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane | HCID 19373268 | — |
Reaction Steps
Using analogous methodology 4-t-butyl-1-(3,3-dimethylbutyl)-2,6,7-trioxabicyclo[2.2.2]octane and 1-(3,3-dimethylbutyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane-3-carbonitrile were prepared from 4,4-dimethylpentanoic acid (G. M. Whitesides et al J. Amer. Chem. Soc. 1967, 89, 1135).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05116862 |
| Source dataset | uspto-grants-1992_05 |
| ORD ID | ord-5ebdd82f2a5e45c3a07955c6bf320bd5 |
| Source note | uspto-grants-1992_05 |