2-Propyl-2-oxetanemethanol → 1-[2-(But-3-ynyloxy)ethyl]-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane

HRID 1197354Notes

Reaction equation

HRID 1197354 reaction equation
[CH2:1]([O:5][CH2:6][CH2:7][C:8]([OH:10])=[O:9])[CH2:2][C:3]#[CH:4].[OH:11][CH2:12][C:13]1([CH2:17][CH2:18][CH3:19])[CH2:16]O[CH2:14]1>>[CH2:1]([O:5][CH2:6][CH2:7][C:8]12[O:11][CH2:12][C:13]([CH2:17][CH2:18][CH3:19])([CH2:16][O:10]1)[CH2:14][O:9]2)[CH2:2][C:3]#[CH:4]

Participants

3

Reactant 2

HCID 1838902-Propyl-2-oxetanemethanolHCID 193734123-(But-3-yn-1-yloxy)propanoic acid

Product 1

HCID 193732971-[2-(But-3-ynyloxy)ethyl]-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane

Procedure

1-[2-(But-3-ynyloxy)ethyl]-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane was prepared from 3-(but-3-ynyloxy)propionic acid and 3-hydroxymethyl-3-n-propyloxetane using the methodology outlined in Example I.

Sources & evidence

ORD record
ord-6ad7ee15c27c4a7994beefa858d69af9
Source dataset
uspto-grants-1992_05
Patent number
US05116862

Reaction notes

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