HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetoacetic Acid → HCID 57176137, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetoacetic Acid | HCID 96 | — |
| Reactant | Diphenylmethane | HCID 7580 | — |
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | HCID 57176137 | HCID 57176137 | — |
Reaction Steps
The title compound is prepared by the microbial oxidation of diphenylmethane by Pseudomonas putida 39D using the method of T. Hudlicky et al. J. Am. Chem. Soc. 110, 4735-41 (1988) and D. Gibson et al. Biochemistry, 9, 1626-30 (1970) followed by protection as the diacetate using acetic anhydride in pyridine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05275950 |
| Source dataset | uspto-grants-1994_01 |
| ORD ID | ord-0b468bdc1d014965bde2fbbfef10a1c9 |
| Source note | uspto-grants-1994_01 |