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HRID1197580

反应详情

EQUATION

反应方程式

HRID 1197580 的结构方程式

REACTANTS

反应物

2
反应SMILES：Cc1ccc(-c2ccccc2C#N)cc1
HCID145512

4'-Methylbiphenyl-2-carbonitrile

C14H11N

反应SMILES：[CH3][Sn]([CH3])([CH3])[N]=[N+]=[N-]
HCID5104973

Azidotrimethyltin(IV)

C3H9N3Sn

PRODUCTS

产物

1
反应SMILES：Cc1ccc(-c2ccccc2-c2nnn[n]2[Sn]([CH3])([CH3])[CH3])cc1
HCID14425662

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
反应SMILES：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

CONDITIONS

反应条件

温度
70 °C

PROCEDURE

实验过程

A solution of 2-cyano-4'-methylbiphenyl (1.93 g) in toluene (25 mL) was treated with trimethyltin azide (2.65 g) and heated at reflux for 24 hours. The resulting suspension was cooled to 70° C. and filtered. The collected solid was dried at reduced pressure to give the title compound. 1H-NMR (CDCl3) δ7.5 (m, 4H), 7.0 (q, 4H), 2.3 (s, 3H), 0.4 (s, 9H).

WORKUP

后处理

  1. temperatureheated
  2. temperatureat reflux for 24 hours
  3. filtrationfiltered
  4. customThe collected solid was dried at reduced pressure