2-Cyano-4'-methylbiphenyl → HCID 14425662, compound

HRID 1197580Notes

Reaction equation

HRID 1197580 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=1)#[N:2].[CH3:16][Sn:17]([N:20]=[N+:21]=[N-:22])([CH3:19])[CH3:18]>C1(C)C=CC=CC=1>[CH3:16][Sn:17]([CH3:19])([CH3:18])[N:20]1[C:1]([C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=2[C:9]2[CH:10]=[CH:11][C:12]([CH3:15])=[CH:13][CH:14]=2)=[N:2][N:22]=[N:21]1

Participants

4

Reactant 2

HCID 1455122-Cyano-4'-methylbiphenylHCID 5104973Azido(trimethyl)stannane

Product 1

HCID 14425662HCID 14425662, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
70 °C

Procedure

A solution of 2-cyano-4'-methylbiphenyl (1.93 g) in toluene (25 mL) was treated with trimethyltin azide (2.65 g) and heated at reflux for 24 hours. The resulting suspension was cooled to 70° C. and filtered. The collected solid was dried at reduced pressure to give the title compound. 1H-NMR (CDCl3) δ7.5 (m, 4H), 7.0 (q, 4H), 2.3 (s, 3H), 0.4 (s, 9H).

Workup

  1. temperatureheated
  2. temperatureat reflux for 24 hours
  3. filtrationfiltered
  4. customThe collected solid was dried at reduced pressure

Sources & evidence

ORD record
ord-12833d536dd04a87901a92f1af15d983
Source dataset
uspto-grants-1994_01
Patent number
US05276048

Reaction notes

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