HuagongsheHuagongshe Chemistry Print Report · For research reference only
9-Acetylanthracene → N-octyl-beta-oxo-9-anthracenepropanamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 9-Acetylanthracene | HCID 69911 | — |
| Reactant | Octyl isocyanate | HCID 76616 | — |
| Reactant | Lithium diisopropylamide | HCID 2724682 | — |
| Product | N-octyl-beta-oxo-9-anthracenepropanamide | HCID 54127851 | — |
Reaction Steps
The title compound, mp 70°-72° C., was prepared from 9-acetylanthracene (5.0 g, 0.022 mol), octyl isocyanate (3.52 g, 0.022 mol), and lithium diisopropylamide (0.032 mol) using the procedure described in Example 1. Purification by flash chromatography (silica gel, 5% EtOAc/hexane) yielded 3.84 g (0.010 mol, 45.2%) of the desired product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05278326 |
| Source dataset | uspto-grants-1994_01 |
| ORD ID | ord-8740323203a848bb8eac714a022d6c3d |
| Source note | uspto-grants-1994_01 |