HRID1198372

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1118

Sulfuric acid

H2O4S

结构：[Cu].c1ccc2c(c1)C1=NC2=NC2=NC(=NC3=NC(=NC4=NC(=N1)c1ccccc14)c1ccccc13)c1ccccc12

HCID475701

未命名化合物

2 次

PRODUCTS

生成物

结构：[Cu].c1ccc2c(c1)-c1nc-2nc2[n-]c(nc3nc(nc4[n-]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID499989

[29H,31H-Phthalocyaninato(2-)-kappaN29,kappaN31]cuprate(2-)

C32H16CuN8-2

PROCEDURE

实验过程

100 Part of crude copper phthalocyanine was treated in 500 parts of a 98% sulfuric acid aqueous solution at room temperature for 2 hours, and filtered. The resultant solid was washed with water and dried to give an α-form crude copper phthalocyanine. Thereafter, the α-form crude copper phthalocyanine was treated in the same way as in Example 1 to give a β-copper phthalocyanine pigment.

WORKUP

后处理

filtrationfiltered
washThe resultant solid was washed with water
customdried
customto give an α-form crude copper phthalocyanine

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d6453113482745a69ba3a0b2a6e27a55
来源数据集: uspto-grants-1994_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05281268
来源说明: uspto-grants-1994_01

反应 SMILES

[CH:1]1[CH:6]=[C:5]2[C:7]3[N:22]=[C:21]([C:4]2=[CH:3][CH:2]=1)[N:20]=[C:19]1[C:23]2[C:28]([C:17](=[N:18]1)[N:16]=[C:15]1[C:29]4[C:34]([C:13](=[N:14]1)[N:12]=[C:11]1[C:35]5[C:40]([C:9](=[N:10]1)[N:8]=3)=[CH:39][CH:38]=[CH:37][CH:36]=5)=[CH:33][CH:32]=[CH:31][CH:30]=4)=[CH:27][CH:26]=[CH:25][CH:24]=2.[Cu:41].S(=O)(=O)(O)O>>[CH:25]1[CH:24]=[C:23]2[C:19]3[N-:18][C:17]([C:28]2=[CH:27][CH:26]=1)=[N:16][C:15]1=[N:14][C:13]([C:34]2[C:29]1=[CH:30][CH:31]=[CH:32][CH:33]=2)=[N:12][C:11]1[N-:10][C:9](=[C:40]2[C:35]=1[CH:36]=[CH:37][CH:38]=[CH:39]2)[N:8]=[C:7]1[C:5]2[C:4]([C:21](=[N:22]1)[N:20]=3)=[CH:3][CH:2]=[CH:1][CH:6]=2.[Cu:41]