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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1198650Generated: October 30, 2026

Styrene → Prop-2-enenitrile--ethenylbenzene (1/1)

https://huagongshe.com/reaction/1198650

Reaction equation

Participants

RoleNameHCIDCharge
ReactantStyreneHCID 7501—
ReactantAcrylonitrileHCID 7855—
ReactantPotassium PersulfateHCID 24412—
ReactantTert-dodecanethiolHCID 32793—
ReactantPotassium OleateHCID 23665571—
SolventWaterHCID 962—
ProductProp-2-enenitrile--ethenylbenzene (1/1)HCID 62696—

Reaction Conditions

Temperature65 °C

Reaction Steps

Separately, a nitrogen-atmosphered reactor was charged with 120 parts of water and 0.3 part of potassium persulfate, and after heating the contents to 65° C., a mixture comprising 70 parts of styrene, 30 parts of acrylonitrile, 0.3 part of t-dodecylmercaptan and 1.5 parts of an aqueous 10% potassium oleate solution was added thereto continuously over 4 hours, followed by polymerization for further 2 hours at 65° C. to obtain a styrene-acrylonitrile copolymer.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05281646
Source datasetuspto-grants-1994_01
ORD IDord-3f4ce753caa546e890fb94fd14764d7e
Source noteuspto-grants-1994_01