HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium borohydride → 16beta-Methyl-5alpha-androstan-17alpha-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | 16beta-Methly-5-androsten-17-one | HCID 54347812 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | 16beta-Methyl-5alpha-androstan-17alpha-ol | HCID 70359541 | — |
| Product | 16beta-Methyl-5alpha-androstan-17beta-ol | HCID 70359622 | — |
Reaction Steps
Similarly, catalytic hydrogenation over 5% palladium on carbon of the 16β-methyl-5-androsten-17-one produced in Example 5 followed by treatment with sodium borohydride affords 16β-methyl-5α-androstan-17α-ol and 16β-methyl-5α-androstan-17β-ol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04898694 |
| Source dataset | uspto-grants-1990_02 |
| ORD ID | ord-500a83e2dbb340e08c7ce3b5cbee8edc |
| Source note | uspto-grants-1990_02 |