Ammonia → HCID 178511992, compound

HRID 1199236Notes

Reaction equation

HRID 1199236 reaction equation
[NH3:1].[C:2]1([NH:8][C:9]([NH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)=S)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.O.O=O>CC([O-])=O.CC([O-])=O.[Cu+2].CO>[C:2]1([NH:8][C:9]([NH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)=[NH:1])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

7

Reactant 4

HCID 222Ammonia2×HCID 962WaterHCID 977OxygenHCID 700999Diphenylthiourea

Product 1

HCID 178511992HCID 178511992, compound

Reagents, catalysts & solvents 2

HCID 8895Cupric acetateCatalystHCID 887MethanolSolvent

Procedure

The amount of ammonia is varied in the following examples. 0.2 mol of diphenylthiourea and ammonia together with 75 g of water, 75 g of methanol, and 0.1 mmol of Cu(OAc)2 are reacted with oxygen (1.5 bar). The other experimental conditions and diphenylguanidine yields are shown in Table 3.

Sources & evidence

ORD record
ord-3367243aa03b47c0b38c87b5bb0f9d4d
Source dataset
uspto-grants-1990_02
Patent number
US04898978

Reaction notes

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