HCID 14696446, compound → HCID 11249146, compound

HRID 1199318Notes

Reaction equation

HRID 1199318 reaction equation
[C:1]([O:9][C@H:10]1[CH2:34][CH2:33][C@@:32]2([CH3:35])[C@@H:12]([CH2:13][CH:14]=[C:15]3[C@@H:31]2[CH2:30][CH2:29][C@@:28]2([CH3:36])[C@@:16]43[O:37][C@H:17]4[CH2:18][C@@H:19]2[C@H:20]([CH3:27])[CH2:21][CH2:22][CH2:23][CH:24]([CH3:26])[CH3:25])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>CC(C)=O>[C:1]([O:9][C@H:10]1[CH2:34][CH2:33][C@@:32]2([CH3:35])[C@@H:12]([CH2:13][CH2:14][C:15]3[C@@H:31]2[CH2:30][CH2:29][C@@:28]2([CH3:36])[C:16]=3[C:17](=[O:37])[CH2:18][C@@H:19]2[C@H:20]([CH3:27])[CH2:21][CH2:22][CH2:23][CH:24]([CH3:26])[CH3:25])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 1

HCID 14696446HCID 14696446, compound

Product 1

HCID 11249146HCID 11249146, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A 5.0 g amount of (3β,5α,15α)-14,15-epoxycholest-7-en-3-ol benzoate (3) (Example 2) was suspended and stirred in 50 ml of acetone and the procedure of Example 6 was followed throughout to obtain 4.8 g of the desired product.

Sources & evidence

ORD record
ord-76d64ae02e0f4e2dbb2ac68295d6126a
Source dataset
uspto-grants-1990_02
Patent number
US04900477

Reaction notes

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