Methanol → 2-(4-Methoxyphenoxy)benzene-1,4-dicarboxylic acid

HRID 1199722Notes

Reaction equation

HRID 1199722 reaction equation
CC1C=CC(S[C:7]2[CH:15]=[C:14]([C:16]([OH:18])=[O:17])[CH:13]=[CH:12][C:8]=2[C:9]([OH:11])=[O:10])=CC=1.CS[C:23]1[CH:28]=[CH:27][C:26]([OH:29])=[CH:25][CH:24]=1.[CH3:30][OH:31]>>[CH3:30][O:31][C:23]1[CH:28]=[CH:27][C:26]([O:29][C:7]2[CH:15]=[C:14]([C:16]([OH:18])=[O:17])[CH:13]=[CH:12][C:8]=2[C:9]([OH:11])=[O:10])=[CH:25][CH:24]=1

Participants

4

Reactant 3

HCID 887MethanolHCID 140864-(Methylthio)phenolHCID 105894221,4-Benzenedicarboxylic acid, 2-[(4-methylphenyl)thio]-

Product 1

HCID 198655232-(4-Methoxyphenoxy)benzene-1,4-dicarboxylic acid

Procedure

2-(4-Methylthiophenoxy)terephthalic acid, m.p. 294°-296° from methanol, from 4-(methylthio)phenol.

Sources & evidence

ORD record
ord-d7f6fb7e0fef46ba990a0c3f9e5128ba
Source dataset
uspto-grants-1990_02
Patent number
US04902701

Reaction notes

Loading…