HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → HCID 178488259, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Ammonium Chloride | HCID 25517 | — |
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | 7-Methoxy-9-oxo-9H-xanthene-3-carbonitrile | HCID 19865524 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 178488259 | HCID 178488259 | — |
Reaction Steps
6-Cyano-2-methoxyxanthone (12.6 g) was heated with sodium azide (3.41 g) and ammonium chloride (2.95 g) in dimethylformamide (100 ml) at 125° for 6 h. The reaction mixture was diluted with water and acidified with excess hydrochloric acid. The precipitated 2-methoxy-6-(5-tetrazolyl)xanthone was filtered off, washed with water, and recrystallised from dimethylformamide, decomposes above 300°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04902701 |
| Source dataset | uspto-grants-1990_02 |
| ORD ID | ord-655e5167407149a48f85ad7ecda39d32 |
| Source note | uspto-grants-1990_02 |