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Hydrogen Sulfide → 4,6-Dimethylpyrimidin-2-ylthiourea
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrogen Sulfide | HCID 402 | — |
| 反応物 | Dichloromethane | HCID 6344 | — |
| 反応物 | (4,6-Dimethylpyrimidin-2-yl)cyanamide | HCID 521618 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 生成物 | 4,6-Dimethylpyrimidin-2-ylthiourea | HCID 747500 | — |
反応手順
A suspension of 10 g of 2-cyanoamino-4,6-dimethylpyrimidine in 50 ml of pyridine was saturated with hydrogen sulfide and stored for 1 hour at 25°. The H2S treatment was repeated twice more, and the mixture was allowed to stir at 25° for 16 hours. Methylene chloride was added, and the product was filtered and washed with methylene chloride to afford 8 g of 4,6-dimethylpyrimidin-2-yl thiourea, m.p. >260°. IR (Nujol) 3280, 3180, 3120, 1610 cm-1.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04904299 |
| 出典データセット | uspto-grants-1990_02 |
| ORD ID | ord-96f5c4c8ef3842fb955baf33b021b241 |
| 出典メモ | uspto-grants-1990_02 |