Ammonia → 6-Hydroxyhexanenitrile

HRID 1200272Notes

Reaction equation

HRID 1200272 reaction equation
[C:1]1(=[O:8])O[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[NH3:9]>>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][C:6]#[N:9].[OH:8][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][C:6]#[N:9]

Participants

4

Reactant 2

HCID 222AmmoniaHCID 10401epsilon-CAPROLACTONE

Product 2

HCID 1232225-HexenenitrileYield 22%HCID 118153226-HydroxyhexanenitrileYield 24%

Procedure

The reaction of epsilon-caprolactone with ammonia in the gas phase over alumina gives 22% of hex-1-ene-6-nitrile and 24% of epsilon-hydroxycapronitrile.

Sources & evidence

ORD record
ord-dcb328a092a94b17aaad6a03b053683f
Source dataset
uspto-grants-1990_02
Patent number
US04904812

Reaction notes

Loading…